Publications

2022 Carboxylic acids as adaptive functional groups in metallaphotoredox catalysis David MacMillan · Accounts of chemical research · Scholar only 274 2022 Metallaphotoredox: the merger of photoredox and transition metal catalysis David MacMillan · Chemical reviews · Scholar only 1,826 2022 Nontraditional fragment couplings of alcohols and carboxylic acids: C (sp3)–C (sp3) cross-coupling via radical sorting David MacMillan · Journal of the American Chemical Society · Scholar only 244 2021 A biomimetic SH2 cross-coupling mechanism for quaternary sp3-carbon formation David MacMillan · Science · Scholar only 239 2021 Metallaphotoredox-enabled deoxygenative arylation of alcohols David MacMillan · Nature · Scholar only 469 2020 Copper-mediated synthesis of drug-like bicyclopentanes David MacMillan · Nature · Scholar only 353 2020 Cross-electrophile coupling of unactivated alkyl chlorides David MacMillan · Journal of the American Chemical Society · Scholar only 265 2020 Mechanistic analysis of metallaphotoredox C–N coupling: photocatalysis initiates and perpetuates Ni (I)/Ni (III) coupling activity David MacMillan · Journal of the American Chemical Society · Scholar only 286 2020 Microenvironment mapping via Dexter energy transfer on immune cells David MacMillan · Science · Scholar only 524 2020 The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation David MacMillan · Nature chemistry · Scholar only 358 2019 The evolution of high-throughput experimentation in pharmaceutical development and perspectives on the future David MacMillan · Organic Process Research & Development · Scholar only 613 2018 A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes David MacMillan · Science · Scholar only 499 2018 Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials David MacMillan · Nature chemistry · Scholar only 420 2018 Decarboxylative sp3 C–N coupling via dual copper and photoredox catalysis David MacMillan · Nature · Scholar only 474 2018 Direct arylation of strong aliphatic C–H bonds David MacMillan · Nature · Scholar only 601 2018 Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α‐Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis David MacMillan · Angewandte Chemie · Scholar only 235 2018 Visible light photocatalysis in organic chemistry David MacMillan · John Wiley & Sons · Scholar only 691 2017 A general small-scale reactor to enable standardization and acceleration of photocatalytic reactions David MacMillan · ACS central science · Scholar only 326 2017 Direct Aldehyde C–H Arylation and Alkylation via the Combination of Nickel, HAT, and Photoredox Catalysis David MacMillan · Journal of the American Chemical Society · Scholar only 337 2017 Direct, enantioselective α-alkylation of aldehydes using simple olefins David MacMillan · Nature Chemistry · Scholar only 236 2017 Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds David MacMillan · Science · Scholar only 579 2017 Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel (II) David MacMillan · Science · Scholar only 631 2017 Selective sp3 C–H alkylation via polarity-match-based cross-coupling David MacMillan · Nature · Scholar only 608 2017 The merger of transition metal and photocatalysis David MacMillan · Nature Reviews Chemistry · Scholar only 2,366 2016 Alcohols as latent coupling fragments for metallaphotoredox catalysis: sp3-sp2 cross-coupling of oxalates with aryl halides David MacMillan · Journal of the American Chemical Society · Scholar only 298 2016 Aryl amination using ligand-free Ni (II) salts and photoredox catalysis David MacMillan · Science · Scholar only 679 2016 Enantioselective decarboxylative arylation of α-amino acids via the merger of photoredox and nickel catalysis David MacMillan · Journal of the American Chemical Society · Scholar only 562 2016 Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides David MacMillan · Nature · Scholar only 513 2016 Native functionality in triple catalytic cross-coupling: sp3 C–H bonds as latent nucleophiles David MacMillan · Science · Scholar only 716 2016 Photoredox catalysis in organic chemistry David MacMillan · The Journal of organic chemistry · Scholar only 3,633 2016 Silyl radical activation of alkyl halides in metallaphotoredox catalysis: a unique pathway for cross-electrophile coupling David MacMillan · Journal of the American Chemical Society · Scholar only 711 2015 Alcohols as alkylating agents in heteroarene C–H functionalization David MacMillan · Nature · Scholar only 761 2015 Decarboxylative fluorination of aliphatic carboxylic acids via photoredox catalysis David MacMillan · Journal of the American Chemical Society · Scholar only 431 2015 Direct α‐Arylation of Ethers through the Combination of Photoredox‐Mediated C H Functionalization and the Minisci Reaction David MacMillan · Angewandte Chemie · Scholar only 489 2015 Merging photoredox and nickel catalysis: decarboxylative cross-coupling of carboxylic acids with vinyl halides David MacMillan · Journal of the American Chemical Society · Scholar only 501 2015 Merging photoredox and nickel catalysis: The direct synthesis of ketones by the decarboxylative arylation of α‐oxo acids David MacMillan · Angewandte Chemie International Edition · Scholar only 360 2015 O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols David MacMillan · Science · Scholar only 629 2015 Oxalates as activating groups for alcohols in visible light photoredox catalysis: formation of quaternary centers by redox-neutral fragment coupling David MacMillan · Journal of the American Chemical Society · Scholar only 436 2015 Selective radical–radical cross-couplings: design of a formal β‑Mannich reaction David MacMillan · Journal of the American Chemical Society · Scholar only 268 2015 Switching on elusive organometallic mechanisms with photoredox catalysis David MacMillan · Nature · Scholar only 711 2015 The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis David MacMillan · Nature · Scholar only 549 2014 Activation of C–H bonds via the merger of photoredox and organocatalysis: a coupling of benzylic ethers with Schiff bases David MacMillan · Journal of the American Chemical Society · Scholar only 320 2014 A general strategy for organocatalytic activation of C–H bonds via photoredox catalysis: direct arylation of benzylic ethers David MacMillan · Journal of the American Chemical Society · Scholar only 323 2014 Carboxylic acids as a traceless activation group for conjugate additions: a three-step synthesis of (±)-pregabalin David MacMillan · Journal of the American Chemical Society · Scholar only 652 2014 Decarboxylative arylation of α-amino acids via photoredox catalysis: a one-step conversion of biomass to drug pharmacophore David MacMillan · Journal of the American Chemical Society · Scholar only 633 2014 Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp3-carbons with aryl halides David MacMillan · Science · Scholar only 1,823 2014 Photoredox α-vinylation of α-amino acids and N-aryl amines David MacMillan · Journal of the American Chemical Society · Scholar only 482 2013 Direct β‑Functionalization of Cyclic Ketones with Aryl Ketones via the Merger of Photoredox and Organocatalysis David MacMillan · Journal of the American Chemical Society · Scholar only 238 2013 Enantioselective Direct α‑Amination of Aldehydes via a Photoredox Mechanism: A Strategy for Asymmetric Amine Fragment Coupling David MacMillan · Journal of the American Chemical Society · Scholar only 295 2013 Photoredox activation for the direct β-arylation of ketones and aldehydes David MacMillan · Science · Scholar only 611