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2025 Alkene-activating effect in molybdenum-catalyzed asymmetric hydrogenation of arenes: Insights into activity and selectivity. Paul Chirik · Journal of the American Chemical Society 4 2025 Iron(III)-mediated C–H alkylation: One-electron differentiation increases activity and chemoselectivity. Paul Chirik · Journal of the American Chemical Society 3 2025 Phenoxyimine iron aryl and alkoxide complexes as reactive intermediates in iron-catalyzed C(sp2)–C(sp3) Suzuki-Miyaura cross coupling. Paul Chirik · Journal of the American Chemical Society 1 2025 Photodriven ammonia synthesis from N2 and H2: Recycling of a molecular molybdenum nitride. Paul Chirik · Journal of the American Chemical Society 16 2025 The role of boron reagents in determining the site-selectivity of pyridine(dicarbene) cobalt-catalyzed C–H borylation of fluorinated arenes. Paul Chirik · Journal of the American Chemical Society 10 2024 A butadiene-derived semicrystalline polyolefin with two-tiered chemical recyclability. Paul Chirik · Chem 26 2024 Ligand field sensitive spin acceleration in the iron-catalyzed [2+2] cycloaddition of unactivated alkenes and dienes. Paul Chirik · Journal of the American Chemical Society 17 2024 (Phenoxyimine)nickel-catalyzed C(sp2)–C(sp3) Suzuki-Miyaura cross coupling: Evidence for a recovering radical chain mechanism. Paul Chirik · Journal of the American Chemical Society 12 2024 Redox-neutral, iron-mediated directed C–H activation: General principles and mechanistic insights. Paul Chirik · Journal of the American Chemical Society 8 2023 Collaboration as a Key to Advance Capabilities for Earth-Abundant Metal Catalysis Paul Chirik · Organic Process Research & Development · Scholar only 78 2023 Iron-Catalyzed C(sp 2 )–C(sp 3 ) Suzuki–Miyaura Cross-Coupling Using an Alkoxide Base Paul Chirik · ACS Catalysis · Scholar only 33 2023 Kinetic and thermodynamic control of C(sp2)–H activation enable site-selective borylation. Paul Chirik · Science 49 2023 Mechanistic investigations of phenoxyimine cobalt(II)-catalyzed C(sp2)–C(sp3) Suzuki-Miyaura cross coupling. Paul Chirik · Journal of the American Chemical Society 30 2022 Alcohol Synthesis by Cobalt-Catalyzed Visible-Light-Driven Reductive Hydroformylation Paul Chirik · Journal of the American Chemical Society · Scholar only 43 2022 Ammonia synthesis by photocatalytic hydrogenation of a N2-derived molybdenum nitride Paul Chirik · Nature Synthesis · Scholar only 57 2022 C–H activation by isolable cationic bis(phosphine) cobalt(III) metallacycles. Paul Chirik · Journal of the American Chemical Society 25 2022 Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Enabled by Well-Defined Precatalysts with L,X-Type Ligands Paul Chirik · ACS Catalysis · Scholar only 38 2022 C(sp2)–H Activation with Bis(silylene)pyridine Cobalt(III) Complexes: Catalytic Hydrogen Isotope Exchange of Sterically Hindered C–H Bonds Paul Chirik · ACS Catalysis · Scholar only 33 2022 Development of Cobalt Catalysts for the meta-Selective C(sp2)–H Borylation of Fluorinated Arenes Paul Chirik · Journal of the American Chemical Society · Scholar only 49 2022 Mechanistic Investigations of the Asymmetric Hydrogenation of Enamides with Neutral Bis(phosphine) Cobalt Precatalysts Paul Chirik · Journal of the American Chemical Society · Scholar only 40 2022 Molybdenum-catalyzed asymmetric hydrogenation of fused arenes and heteroarenes. Paul Chirik · Journal of the American Chemical Society 63 2022 Three-Component Coupling of Arenes, Ethylene, and Alkynes Catalyzed by a Cationic Bis(phosphine) Cobalt Complex: Intercepting Metallacyclopentenes for C–H Functionalization Paul Chirik · Journal of the American Chemical Society · Scholar only 55 2021 A Tutorial on Selectivity Determination in C(sp2)–H Oxidative Addition of Arenes by Transition Metal Complexes Paul Chirik · Organometallics · Scholar only 51 2021 Green Chemistry: A Framework for a Sustainable Future Paul Chirik · The Journal of Organic Chemistry · Scholar only · needs review 260 2021 Iron catalyzed synthesis and chemical recycling of telechelic 1,3-enchained oligocyclobutanes. Paul Chirik · Nature Chemistry 86 2021 Synthesis, Electronic Structure, and Reactivity of a Planar Four‐Coordinate, Cobalt–Imido Complex Paul Chirik · Angewandte Chemie · Scholar only · needs review 45 2021 Visible light enables catalytic formation of weak chemical bonds with molecular hydrogen. Paul Chirik · Nature Chemistry 62 2021 Visible-Light-Enhanced Cobalt-Catalyzed Hydrogenation: Switchable Catalysis Enabled by Divergence between Thermal and Photochemical Pathways Paul Chirik · ACS Catalysis · Scholar only 52 2020 A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes Paul Chirik · Journal of the American Chemical Society · Scholar only 82 2020 Beyond Ammonia: Nitrogen–Element Bond Forming Reactions with Coordinated Dinitrogen Paul Chirik · Chemical Reviews · Scholar only 287 2020 Catalytic Hydrogenation of a Manganese(V) Nitride to Ammonia Paul Chirik · Journal of the American Chemical Society · Scholar only 37 2020 Cobalt-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Carboxylic Acids by Homolytic H 2 Cleavage Paul Chirik · Journal of the American Chemical Society · Scholar only 122 2020 Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross Coupling Paul Chirik · Organic Letters · Scholar only 59 2020 C(sp2)–H Activation with Pyridine Dicarbene Iron Dialkyl Complexes: Hydrogen Isotope Exchange of Arenes Using Benzene-d6 as a Deuterium Source Paul Chirik · ACS Catalysis · Scholar only 60 2020 C(sp2)–H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)–H Activation, and Catalytically Relevant Intermediates Paul Chirik · Organometallics · Scholar only 43 2020 Investigations into the Mechanism of Inter- and Intramolecular Iron-Catalyzed [2 + 2] Cycloaddition of Alkenes Paul Chirik · Journal of the American Chemical Society · Scholar only 55 2020 Ketone Synthesis from Benzyldiboronates and Esters: Leveraging α-Boryl Carbanions for Carbon–Carbon Bond Formation Paul Chirik · Journal of the American Chemical Society · Scholar only 75 2020 Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp2)-H Borylation of Benzoate Esters and Arylboronate Esters Paul Chirik · Chem · Scholar only 33 2020 Synthesis and Reactivity of Organometallic Intermediates Relevant to Cobalt‐Catalyzed Hydroformylation Paul Chirik · Angewandte Chemie · Scholar only · needs review 32 2020 Using nature’s blueprint to expand catalysis with Earth-abundant metals Paul Chirik · Science · Scholar only 655 2019 [4 + 4]-cycloaddition of isoprene for the production of high-performance bio-based jet fuel Paul Chirik · Green Chemistry · Scholar only 72 2019 Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp2)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity Paul Chirik · Journal of the American Chemical Society · Scholar only 88 2019 Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications Paul Chirik · Journal of the American Chemical Society · Scholar only 174 2019 Hydrogenation of N-Heteroarenes Using Rhodium Precatalysts: Reductive Elimination Leads to Formation of Multimetallic Clusters Paul Chirik · Journal of the American Chemical Society · Scholar only 91 2019 N–H Bond Formation in a Manganese(V) Nitride Yields Ammonia by Light-Driven Proton-Coupled Electron Transfer Paul Chirik · Journal of the American Chemical Society · Scholar only 80 2019 Ni(I)–X Complexes Bearing a Bulky α-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals Paul Chirik · Journal of the American Chemical Society · Scholar only 155 2019 Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand Paul Chirik · Organometallics · Scholar only 39 2019 Pyridine(diimine) Iron Diene Complexes Relevant to Catalytic [2+2]‐Cycloaddition Reactions Paul Chirik · Advanced Synthesis & Catalysis · Scholar only 34 2019 Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes Paul Chirik · Journal of the American Chemical Society · Scholar only 93 2019 Remote, Diastereoselective Cobalt-Catalyzed Alkene Isomerization–Hydroboration: Access to Stereodefined 1,3-Difunctionalized Indanes Paul Chirik · ACS Catalysis · Scholar only 66
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2025 · article · journal

Alkene-activating effect in molybdenum-catalyzed asymmetric hydrogenation of arenes: Insights into activity and selectivity.

Journal of the American Chemical Society · Paul Chirik

in CV in OpenAlex
noneScholar citations
4OpenAlex citations

From the CV

lines 102–104 · published

19. Greenbaum, J. C.; King, A. J.; Pecoraro, M. V.; Tosatti, P.; Puentener, K.; Chirik, P. J.“Alkene-activating effect in molybdenum-catalyzed asymmetric hydrogenation of arenes:Insights into activity and selectivity.” J. Am. Chem. Soc. 2025, 147, 30423-30435.

Peer reviewed
yes
First author
Greenbaum
Co-authors
Greenbaum, J. C.; King, A. J.; Pecoraro, M. V.; Tosatti, P.; Puentener, K.; Chirik, P. J.
Subfield
other
Method
none
Invited
none
Publisher
none
Reprint or translation
none
DOI
10.1021/jacs.5c10499
OpenAlex
W4413107022

Where each field came from

FieldCVOpenAlexScholarCrossRef
title Alkene-activating effect in molybdenum-catalyzed asymmetric hydrogenation of arenes: Insights into activity and selectivity. (used)Alkene-Activating Effect in Molybdenum-Catalyzed Asymmetric Hydrogenation of Arenes: Insights into Activity and Selectivity
year 2025 (used)2025
venue J. Am. Chem. Soc.Journal of the American Chemical SocietyJournal of the American Chemical Society (used)
kind article (used)article
DOI 10.1021/jacs.5c10499 (used)10.1021/jacs.5c10499
first author GreenbaumGreenbaum (used)

The value in bold is the one the record uses.

How the records were joined

  • doi merged · 1.00 · Run 18